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sector:ippu:chemical_industry:other:start [2022/03/10 10:53] – [Table] zheng | sector:ippu:chemical_industry:other:start [2024/11/06 13:54] (current) – external edit 127.0.0.1 | ||
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__Table 1: Overview of emission sources covered__ | __Table 1: Overview of emission sources covered__ | ||
- | ^ Emission sources | + | ^ Emission sources |
- | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] | + | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] |
- | | [[#Carbon Black|Carbon Black]] | + | | [[#Carbon Black|Carbon Black]] |
- | | [[#Fertilizers|Fertilizers]] | + | | [[#fertilizer_production|Fertilizers]] |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
{{page> | {{page> | ||
===== Method ===== | ===== Method ===== | ||
- | === Large Volume Organic | + | ==== Large volume organic |
The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | ||
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__Table 2: national NMVOC emission factors for producing organic chemicals, in kg/t__ | __Table 2: national NMVOC emission factors for producing organic chemicals, in kg/t__ | ||
- | ^ Product | + | ^ ^ Acrylonitrile |
- | ^ from 1990-1994 | + | ^ 1990-1994 |
- | ^ 1995 | 0.07 | 0.02 | 0.4 | C | 0.06 | 0.02 | 0.04 | 0.2 | 0.2 | 0.02 | 0.2 | | + | ^ 1995 |
- | ^ 1996 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1996 |
- | ^ 1997 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1997 |
- | ^ 1998 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1998 |
- | ^ 1999 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1999 |
- | ^ from 2000 | + | ^ from 2000 | 0.035 | 0.01 | 0.2 |
__Table 3: national NMVOC emission factors for producing polymers, in kg/t__ | __Table 3: national NMVOC emission factors for producing polymers, in kg/t__ | ||
- | ^ products | + | ^ ^ Polyethylene (PE) |
- | ^ | + | ^ | Low density (LD) |
- | ^ from 1990 to 1994 | + | ^ 1990-1994 | 8 | 6 | 8 | 1 |
- | ^ 1995 | 2.2 | 1 | 1 | 0.6 | 0.25 | 0.6 | | + | ^ 1995 |
- | ^ 1996 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1996 |
- | ^ 1997 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1997 |
- | ^ 1998 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1998 |
- | ^ 1999 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1999 |
- | ^ from 2000 | + | ^ from 2000 | 1.1 | 0.5 | 0.5 | 0.27 | 0.14 | 0.3 | |
- | === Carbon Black === | + | ==== Carbon Black ==== |
The figures for carbon black production in the new German Länder in 1990 were taken from the Statistical Yearbook (Statistisches Jahrbuch) for the Federal Republic of Germany; the figures for 1991 and 1992 were estimated, due to confidentiality requirements. The other data for carbon-black production as of 1990 were obtained from national production statistics< | The figures for carbon black production in the new German Länder in 1990 were taken from the Statistical Yearbook (Statistisches Jahrbuch) for the Federal Republic of Germany; the figures for 1991 and 1992 were estimated, due to confidentiality requirements. The other data for carbon-black production as of 1990 were obtained from national production statistics< | ||
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__Table 4: Emission factors of carbon black in Germany, in kg/t__ | __Table 4: Emission factors of carbon black in Germany, in kg/t__ | ||
- | ^ Pollutant | + | ^ ^ CO ^ SO< |
- | ^ 1990 | 4.80 | 19.16 | 0.28 | | + | ^ 1990 |
- | ^ 1991 | 4.60 | 19.01 | 0.28 | | + | ^ 1991 |
- | ^ 1992 | 4.40 | 18.50 | + | ^ 1992 |
- | ^ 1993 | 4.20 | 18.00 | 0.26 | | + | ^ 1993 |
- | ^ 1994 | 4.00 | 17.50 | + | ^ 1994 |
- | ^ 1995 | 3.75 | 17.00 | 0.25 | 0.23 | 0.12 | + | ^ 1995 |
- | ^ 1996 | 3.50 | 16.00 | 0.25 | 0.23 | + | ^ 1996 |
- | ^ 1997 | 3.25 | 15.00 | 0.25 | 0.23 | + | ^ 1997 |
- | ^ 1998 | 3.00 | 14.00 | 0.25 | 0.23 | + | ^ 1998 |
- | ^ 1999 | 2.90 | 13.40 | 0.25 | 0.23 | + | ^ 1999 |
- | ^ 2000 | 2.80 | 12.80 | 0.25 | 0.23 | + | ^ 2000 |
- | ^ 2001 | 2.70 | 12.54 | 0.25 | 0.23 | + | ^ 2001 |
- | ^ 2002 | 2.65 | 12.28 | 0.25 | 0.23 | 0.12 | + | ^ 2002 |
- | ^ 2003 | 2.60 | 12.00 | 0.25 | 0.23 | 0.12 | + | ^ 2003 |
- | ^ 2004 | 2.55 | 11.70 | 0.25 | 0.23 | + | ^ 2004 |
- | ^ 2005 | 2.50 | 11.50 | 0.25 | 0.23 | + | ^ 2005 |
- | ^ 2006 | 2.50 | 11.20 | 0.24 | 0.22 | + | ^ 2006 |
- | ^ 2007 | 2.50 | 10.90 | 0.23 | 0.21 | + | ^ 2007 |
- | ^ 2008 | 2.50 | 10.60 | 0.22 | 0.20 | + | ^ 2008 |
- | ^ 2009 | 2.50 | 10.30 | 0.21 | 0.19 | + | ^ 2009 |
- | ^ from 2010 | 2.50 | 10.00 | 0.20 | 0.18 | 0.10 | + | ^ from 2010 | 2.50 | 10.00 |
- | === Fertilizer production === | + | ==== Fertilizer production |
- | The activity data is also extracted from national production statistics by the Federal Statistical Office< | + | The activity data is also extracted from national production statistics by the Federal Statistical Office< |
The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | ||
- | __Table 5: Emission factors of fertilizers in Germany, in kg/t__ | + | __Table 5: Emission factors of fertilizers in Germany__ |
- | ^ Product | + | ^ ^ PM< |
- | ^ Pollutant | + | ^ 1990 |
- | ^ 1990 | + | ^ 1991-1994 | NA |
- | ^ from 1991 to 1994 | NA | NA | 2 | | + | ^ from 1995 | 0.115938 |
- | ^ from 1995 onwards | + | |
- | === Urea production === | + | ==== Urea production |
The activity data is from the federal statistical office of Germany (GP 2015 31 300). The amount of urea is reported there in t-N. | The activity data is from the federal statistical office of Germany (GP 2015 31 300). The amount of urea is reported there in t-N. | ||
- | As the emission factor is in kg/t urea the reported amount of urea in t-N is multiplied with the molar mass of urea and divided with the molar mass of nitric (60,06/ | + | As the emission factor is in kg/t urea, the reported amount of urea in t-N is multiplied with the molar mass of urea and divided with the molar mass of nitric (60.06/ |
- | ARurea | + | AR of urea (in t) = AR of urea (in t-N) * (molar mass of urea)/ (molar mass of N) |
- | The emission factor is a T2 EF from the EMEP/EEA Guidebook 2019, chapter 3.2.2, | + | The emission factor |
- | The value is 2.5 kg /t urea | + | |
- | === Sulphuric acid === | + | ==== Sulphuric acid ==== |
The activity data for sulphuric acid production is from the Federal Statistical Office of Germany. | The activity data for sulphuric acid production is from the Federal Statistical Office of Germany. | ||
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For the SO< | For the SO< | ||
- | === Chlor-alkali industry === | + | ==== Chlor-alkali industry ==== |
+ | |||
+ | For the mercury (Hg) losses from the Chlor-alkali industry, Germany used the yearly published data from OSPAR [(ODIMS (OSPAR Data & Information Management System); https:// | ||
+ | However, emissions of Hg are still ocurring, because two production sites still continue to uses the amalgam process for the production of certain alcoholates; | ||
+ | As from 2018 PRTR data is used to determine mercury emissions belonging to the alcoholate production. Due to a delay of the 2019 PRTR data the 2018 emission value is used also in 2019 and 2020. | ||
- | For the mercury losses from the Chlor-alkali industry, Germany uses the yearly published data from OSPAR on the plant specific production capacity for the AD and the plant specific emissions from the chlor-alkali industry. Because of the BAT (best available technique) conclusion for the Chlor-alkali industry, the production has stopped in 2017. However, emissions of Hg are still ocurring, because two plants still produce alcoholates and dithionite and are not regulated by the BAT conclusions for Chlor-alkali production. In both plants Chlor-alkali was also produced. The Hg-emissions from the production of dithionite and alcoholates | ||
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For SO< | For SO< | ||
- | From Submission 2022 the SO< | + | From Submission 2022 onwards, |
- | + | ||
- | **Table 6**: SO< | + | |
- | ^ Year ^ SO< | + | |
- | | 1990 | 23.47 | | + | |
- | | 1991 | 22.47 | | + | |
- | | 1992 | 22.07 | | + | |
- | | 1993 | 20.14 | | + | |
- | | 1994 | 18.86 | | + | |
- | | 1995 | 23.03 | | + | |
- | | 1996 | 20.98 | | + | |
- | | 1997 | 22.23 | | + | |
- | | 1998 | 23.58 | | + | |
- | | 1999 | 24.03 | | + | |
- | | 2000 | 24.04 | | + | |
- | | 2001 | 23.01 | | + | |
- | | 2002 | 22.89 | | + | |
- | | 2003 | 23.78 | | + | |
- | | 2004 | 25.65 | | + | |
- | | 2005 | 26.54 | | + | |
- | | 2006 | 26.83 | | + | |
- | | 2007 | 25.74 | | + | |
- | | 2008 | 24.1 | | + | |
- | | 2009 | 19.87 | | + | |
- | | 2010 | 20.39 | | + | |
- | | 2011 | 19.79 | | + | |
- | | 2012 | 18.25 | | + | |
- | | 2013 | 16.94 | | + | |
- | | 2014 | 13.89 | | + | |
- | | 2015 | 12.59 | | + | |
- | | 2016 | 11.06 | | + | |
- | | 2017 | 10.14 | | + | |
- | | 2018 | 10.22 | | + | |
- | | 2019 | 9.96 | | + | |
- | | 2020 | 9.69 | | + | |
- | + | ||
- | So far Germany | + | |
- | Therefore, instead of nitric fertilizer production Germany reports NH< | + | |
- | **Table 7**: NH<sub>3</ | + | Otherwise no recalculations of SO<sub>2</ |
- | ^ ^ Subm2022 | + | |
- | ^ Product | + | |
- | ^ ^ AD ^ EM ^ AD ^ EM ^ EM ^ EM ^ EM ^ | + | |
- | ^ Pollutant | + | |
- | ^ Unit ^ t ^ t ^ t ^ t ^ t ^ t ^ t ^ | + | |
- | ^ 1990 | 2.574.000 | + | |
- | ^ 1991 | 2.574.000 | + | |
- | ^ 1992 | 2.574.000 | + | |
- | ^ 1993 | 2.574.000 | + | |
- | ^ 1994 | 2.574.000 | + | |
- | ^ 1995 | 2.438.937, | + | |
- | ^ 1996 | 2.607.500, | + | |
- | ^ 1997 | 2.344.506, | + | |
- | ^ 1998 | 2.468.749, | + | |
- | ^ 1999 | 2.463.343, | + | |
- | ^ 2000 | 2.646.492, | + | |
- | ^ 2001 | 2.333.532, | + | |
- | ^ 2002 | 2.830.276, | + | |
- | ^ 2003 | 2.801.352, | + | |
- | ^ 2004 | 2.435.604, | + | |
- | ^ 2005 | 2.587.955, | + | |
- | ^ 2006 | 2.854.574, | + | |
- | ^ 2007 | 2.648.474, | + | |
- | ^ 2008 | 2.592.549, | + | |
- | ^ 2009 | 3.422.832, | + | |
- | ^ 2010 | 3.074.359, | + | |
- | ^ 2011 | 1.854.138 | + | |
- | ^ 2012 | 1.819.491, | + | |
- | ^ 2013 | 1.716.231, | + | |
- | ^ 2014 | 1.691.259, | + | |
- | ^ 2015 | 1.369.174, | + | |
- | ^ 2016 | 1.733.301, | + | |
- | ^ 2017 | 2.237.758, | + | |
- | ^ 2018 | 2.161.469, | + | |
- | ^ 2019 | 2.129.006, | + | |
- | ^ 2020 | 2.124.257, | + | |
- | <WRAP center round info 100%> | + | <WRAP center round info 65%> |
- | For specific | + | For **pollutant-specific |
</ | </ | ||
===== Planned improvements ===== | ===== Planned improvements ===== | ||
- | For the mercury losses from the Chlor-alkali industry, because of the BAT conclusion for the Chlor-alkali industry the production has stopped in 2017. However, emissions of Hg are still ocurring, because two plants are still producing alcoholates and dithionite and were so far reported by CEFIC to OSPAR based on BAT regulation for Chlor-alkali production. Since the OSPAR convention does not request to report the Hg-emissions from dithionite and alcoholate production, CEFIC no longer reports these emissions to OSPAR. | + | There are no planned improvements. |
- | Germany is trying to ensure reporting of Hg emissions for that sources. | + | |