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sector:ippu:chemical_industry:other:start [2022/03/16 09:08] – [Table] kuntze | sector:ippu:chemical_industry:other:start [2024/11/06 13:54] (current) – external edit 127.0.0.1 | ||
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__Table 1: Overview of emission sources covered__ | __Table 1: Overview of emission sources covered__ | ||
- | ^ Emission sources | + | ^ Emission sources |
- | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] | + | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] |
- | | [[#Carbon Black|Carbon Black]] | + | | [[#Carbon Black|Carbon Black]] |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
{{page> | {{page> | ||
===== Method ===== | ===== Method ===== | ||
- | ==== Large Volume Organic | + | ==== Large volume organic |
The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | ||
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__Table 2: national NMVOC emission factors for producing organic chemicals, in kg/t__ | __Table 2: national NMVOC emission factors for producing organic chemicals, in kg/t__ | ||
- | ^ Product | + | ^ ^ Acrylonitrile |
- | ^ from 1990-1994 | + | ^ 1990-1994 |
- | ^ 1995 | 0.07 | 0.02 | 0.4 | C | 0.06 | 0.02 | 0.04 | 0.2 | 0.2 | 0.02 | 0.2 | | + | ^ 1995 |
- | ^ 1996 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1996 |
- | ^ 1997 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1997 |
- | ^ 1998 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1998 |
- | ^ 1999 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1999 |
- | ^ from 2000 | + | ^ from 2000 | 0.035 | 0.01 | 0.2 |
__Table 3: national NMVOC emission factors for producing polymers, in kg/t__ | __Table 3: national NMVOC emission factors for producing polymers, in kg/t__ | ||
- | ^ products | + | ^ ^ Polyethylene (PE) |
- | ^ | + | ^ | Low density (LD) |
- | ^ from 1990 to 1994 | + | ^ 1990-1994 | 8 | 6 | 8 | 1 |
- | ^ 1995 | 2.2 | 1 | 1 | 0.6 | 0.25 | 0.6 | | + | ^ 1995 |
- | ^ 1996 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1996 |
- | ^ 1997 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1997 |
- | ^ 1998 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1998 |
- | ^ 1999 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1999 |
- | ^ from 2000 | + | ^ from 2000 | 1.1 | 0.5 | 0.5 | 0.27 | 0.14 | 0.3 | |
==== Carbon Black ==== | ==== Carbon Black ==== | ||
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__Table 4: Emission factors of carbon black in Germany, in kg/t__ | __Table 4: Emission factors of carbon black in Germany, in kg/t__ | ||
- | ^ Pollutant | + | ^ ^ CO ^ SO< |
- | ^ 1990 | 4.80 | 19.16 | 0.28 | | + | ^ 1990 |
- | ^ 1991 | 4.60 | 19.01 | 0.28 | | + | ^ 1991 |
- | ^ 1992 | 4.40 | 18.50 | + | ^ 1992 |
- | ^ 1993 | 4.20 | 18.00 | 0.26 | | + | ^ 1993 |
- | ^ 1994 | 4.00 | 17.50 | + | ^ 1994 |
- | ^ 1995 | 3.75 | 17.00 | 0.25 | 0.23 | 0.12 | + | ^ 1995 |
- | ^ 1996 | 3.50 | 16.00 | 0.25 | 0.23 | + | ^ 1996 |
- | ^ 1997 | 3.25 | 15.00 | 0.25 | 0.23 | + | ^ 1997 |
- | ^ 1998 | 3.00 | 14.00 | 0.25 | 0.23 | + | ^ 1998 |
- | ^ 1999 | 2.90 | 13.40 | 0.25 | 0.23 | + | ^ 1999 |
- | ^ 2000 | 2.80 | 12.80 | 0.25 | 0.23 | + | ^ 2000 |
- | ^ 2001 | 2.70 | 12.54 | 0.25 | 0.23 | + | ^ 2001 |
- | ^ 2002 | 2.65 | 12.28 | 0.25 | 0.23 | 0.12 | + | ^ 2002 |
- | ^ 2003 | 2.60 | 12.00 | 0.25 | 0.23 | 0.12 | + | ^ 2003 |
- | ^ 2004 | 2.55 | 11.70 | 0.25 | 0.23 | + | ^ 2004 |
- | ^ 2005 | 2.50 | 11.50 | 0.25 | 0.23 | + | ^ 2005 |
- | ^ 2006 | 2.50 | 11.20 | 0.24 | 0.22 | + | ^ 2006 |
- | ^ 2007 | 2.50 | 10.90 | 0.23 | 0.21 | + | ^ 2007 |
- | ^ 2008 | 2.50 | 10.60 | 0.22 | 0.20 | + | ^ 2008 |
- | ^ 2009 | 2.50 | 10.30 | 0.21 | 0.19 | + | ^ 2009 |
- | ^ from 2010 | 2.50 | 10.00 | 0.20 | 0.18 | 0.10 | + | ^ from 2010 | 2.50 | 10.00 |
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The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | ||
- | __Table 5: Emission factors of fertilizers in Germany, in kg/t__ | + | __Table 5: Emission factors of fertilizers in Germany__ |
- | ^ Product | + | ^ ^ PM< |
- | ^ Pollutant | + | ^ 1990 |
- | ^ 1990 | + | ^ 1991-1994 | NA |
- | ^ from 1991 to 1994 | NA | NA | 2 | | + | ^ from 1995 | 0.115938 |
- | ^ from 1995 onwards | + | |
==== Urea production ==== | ==== Urea production ==== | ||
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==== Chlor-alkali industry ==== | ==== Chlor-alkali industry ==== | ||
- | For the mercury losses from the Chlor-alkali industry, Germany | + | For the mercury |
+ | However, emissions of Hg are still ocurring, because two production sites still continue to uses the amalgam process for the production of certain | ||
+ | As from 2018 PRTR data is used to determine mercury emissions belonging to the alcoholate production. Due to a delay of the 2019 PRTR data the 2018 emission value is used also in 2019 and 2020. | ||
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For SO< | For SO< | ||
- | From Submission 2022 the SO< | + | From Submission 2022 onwards, |
- | + | ||
- | **Table 6**: SO< | + | |
- | ^ Year ^ SO< | + | |
- | | 1990 | 23.47 | | + | |
- | | 1991 | 22.47 | | + | |
- | | 1992 | 22.07 | | + | |
- | | 1993 | 20.14 | | + | |
- | | 1994 | 18.86 | | + | |
- | | 1995 | 23.03 | | + | |
- | | 1996 | 20.98 | | + | |
- | | 1997 | 22.23 | | + | |
- | | 1998 | 23.58 | | + | |
- | | 1999 | 24.03 | | + | |
- | | 2000 | 24.04 | | + | |
- | | 2001 | 23.01 | | + | |
- | | 2002 | 22.89 | | + | |
- | | 2003 | 23.78 | | + | |
- | | 2004 | 25.65 | | + | |
- | | 2005 | 26.54 | | + | |
- | | 2006 | 26.83 | | + | |
- | | 2007 | 25.74 | | + | |
- | | 2008 | 24.1 | | + | |
- | | 2009 | 19.87 | | + | |
- | | 2010 | 20.39 | | + | |
- | | 2011 | 19.79 | | + | |
- | | 2012 | 18.25 | | + | |
- | | 2013 | 16.94 | | + | |
- | | 2014 | 13.89 | | + | |
- | | 2015 | 12.59 | | + | |
- | | 2016 | 11.06 | | + | |
- | | 2017 | 10.14 | | + | |
- | | 2018 | 10.22 | | + | |
- | | 2019 | 9.96 | | + | |
- | | 2020 | 9.69 | | + | |
- | + | ||
- | So far Germany | + | |
- | Therefore, instead of nitric fertilizer production Germany reports NH< | + | |
- | **Table 7**: NH<sub>3</ | + | Otherwise no recalculations of SO<sub>2</ |
- | ^ ^ Subm2022 | + | |
- | ^ Product | + | |
- | ^ ^ AD ^ EM ^ AD ^ EM ^ EM ^ EM ^ EM ^ | + | |
- | ^ Pollutant | + | |
- | ^ Unit ^ t ^ t ^ t ^ t ^ t ^ t ^ t ^ | + | |
- | ^ 1990 | 2, | + | |
- | ^ 1991 | 2, | + | |
- | ^ 1992 | 2, | + | |
- | ^ 1993 | 2, | + | |
- | ^ 1994 | 2, | + | |
- | ^ 1995 | 2, | + | |
- | ^ 1996 | 2, | + | |
- | ^ 1997 | 2, | + | |
- | ^ 1998 | 2, | + | |
- | ^ 1999 | 2, | + | |
- | ^ 2000 | 2, | + | |
- | ^ 2001 | 2, | + | |
- | ^ 2002 | 2, | + | |
- | ^ 2003 | 2, | + | |
- | ^ 2004 | 2, | + | |
- | ^ 2005 | 2, | + | |
- | ^ 2006 | 2, | + | |
- | ^ 2007 | 2, | + | |
- | ^ 2008 | 2, | + | |
- | ^ 2009 | 3, | + | |
- | ^ 2010 | 3, | + | |
- | ^ 2011 | 1, | + | |
- | ^ 2012 | 1, | + | |
- | ^ 2013 | 1, | + | |
- | ^ 2014 | 1, | + | |
- | ^ 2015 | 1, | + | |
- | ^ 2016 | 1, | + | |
- | ^ 2017 | 2, | + | |
- | ^ 2018 | 2, | + | |
- | ^ 2019 | 2, | + | |
- | ^ 2020 | 2, | + | |
- | <WRAP center round info 100%> | + | <WRAP center round info 65%> |
- | For specific | + | For **pollutant-specific |
</ | </ | ||
===== Planned improvements ===== | ===== Planned improvements ===== | ||
- | For the mercury losses from the Chlor-alkali industry, because of the BAT conclusion for the Chlor-alkali industry the production has stopped in 2017. However, emissions of Hg are still ocurring, because two plants are still producing alcoholates and dithionite and were so far reported by CEFIC to OSPAR based on BAT regulation for Chlor-alkali production. Since the OSPAR convention does not request to report the Hg-emissions from dithionite and alcoholate production, CEFIC no longer reports these emissions to OSPAR. | + | There are no planned improvements. |
- | Germany is trying to ensure reporting of Hg emissions for that sources. | + | |