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sector:ippu:chemical_industry:other:start [2022/03/29 09:35] – [Planned improvements] reichel | sector:ippu:chemical_industry:other:start [2024/11/06 13:54] (current) – external edit 127.0.0.1 | ||
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__Table 1: Overview of emission sources covered__ | __Table 1: Overview of emission sources covered__ | ||
- | ^ Emission sources | + | ^ Emission sources |
- | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] | + | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] |
- | | [[#Carbon Black|Carbon Black]] | + | | [[#Carbon Black|Carbon Black]] |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
{{page> | {{page> | ||
===== Method ===== | ===== Method ===== | ||
- | ==== Large Volume Organic | + | ==== Large volume organic |
The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | ||
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__Table 2: national NMVOC emission factors for producing organic chemicals, in kg/t__ | __Table 2: national NMVOC emission factors for producing organic chemicals, in kg/t__ | ||
- | ^ Product | + | ^ ^ Acrylonitrile |
- | ^ from 1990-1994 | + | ^ 1990-1994 |
- | ^ 1995 | 0.07 | 0.02 | 0.4 | C | 0.06 | 0.02 | 0.04 | 0.2 | 0.2 | 0.02 | 0.2 | | + | ^ 1995 |
- | ^ 1996 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1996 |
- | ^ 1997 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1997 |
- | ^ 1998 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1998 |
- | ^ 1999 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1999 |
- | ^ from 2000 | + | ^ from 2000 | 0.035 | 0.01 | 0.2 |
__Table 3: national NMVOC emission factors for producing polymers, in kg/t__ | __Table 3: national NMVOC emission factors for producing polymers, in kg/t__ | ||
- | ^ products | + | ^ ^ Polyethylene (PE) |
- | ^ | + | ^ | Low density (LD) |
- | ^ from 1990 to 1994 | + | ^ 1990-1994 | 8 | 6 | 8 | 1 |
- | ^ 1995 | 2.2 | 1 | 1 | 0.6 | 0.25 | 0.6 | | + | ^ 1995 |
- | ^ 1996 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1996 |
- | ^ 1997 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1997 |
- | ^ 1998 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1998 |
- | ^ 1999 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1999 |
- | ^ from 2000 | + | ^ from 2000 | 1.1 | 0.5 | 0.5 | 0.27 | 0.14 | 0.3 | |
==== Carbon Black ==== | ==== Carbon Black ==== | ||
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__Table 4: Emission factors of carbon black in Germany, in kg/t__ | __Table 4: Emission factors of carbon black in Germany, in kg/t__ | ||
- | ^ Pollutant | + | ^ ^ CO ^ SO< |
- | ^ 1990 | 4.80 | 19.16 | 0.28 | | + | ^ 1990 |
- | ^ 1991 | 4.60 | 19.01 | 0.28 | | + | ^ 1991 |
- | ^ 1992 | 4.40 | 18.50 | + | ^ 1992 |
- | ^ 1993 | 4.20 | 18.00 | 0.26 | | + | ^ 1993 |
- | ^ 1994 | 4.00 | 17.50 | + | ^ 1994 |
- | ^ 1995 | 3.75 | 17.00 | 0.25 | 0.23 | 0.12 | + | ^ 1995 |
- | ^ 1996 | 3.50 | 16.00 | 0.25 | 0.23 | + | ^ 1996 |
- | ^ 1997 | 3.25 | 15.00 | 0.25 | 0.23 | + | ^ 1997 |
- | ^ 1998 | 3.00 | 14.00 | 0.25 | 0.23 | + | ^ 1998 |
- | ^ 1999 | 2.90 | 13.40 | 0.25 | 0.23 | + | ^ 1999 |
- | ^ 2000 | 2.80 | 12.80 | 0.25 | 0.23 | + | ^ 2000 |
- | ^ 2001 | 2.70 | 12.54 | 0.25 | 0.23 | + | ^ 2001 |
- | ^ 2002 | 2.65 | 12.28 | 0.25 | 0.23 | 0.12 | + | ^ 2002 |
- | ^ 2003 | 2.60 | 12.00 | 0.25 | 0.23 | 0.12 | + | ^ 2003 |
- | ^ 2004 | 2.55 | 11.70 | 0.25 | 0.23 | + | ^ 2004 |
- | ^ 2005 | 2.50 | 11.50 | 0.25 | 0.23 | + | ^ 2005 |
- | ^ 2006 | 2.50 | 11.20 | 0.24 | 0.22 | + | ^ 2006 |
- | ^ 2007 | 2.50 | 10.90 | 0.23 | 0.21 | + | ^ 2007 |
- | ^ 2008 | 2.50 | 10.60 | 0.22 | 0.20 | + | ^ 2008 |
- | ^ 2009 | 2.50 | 10.30 | 0.21 | 0.19 | + | ^ 2009 |
- | ^ from 2010 | 2.50 | 10.00 | 0.20 | 0.18 | 0.10 | + | ^ from 2010 | 2.50 | 10.00 |
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The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | ||
- | __Table 5: Emission factors of fertilizers in Germany, in kg/t__ | + | __Table 5: Emission factors of fertilizers in Germany__ |
- | ^ Product | + | ^ ^ PM< |
- | ^ Pollutant | + | ^ 1990 |
- | ^ 1990 | + | ^ 1991-1994 | NA |
- | ^ from 1991 to 1994 | NA | NA | 2 | | + | ^ from 1995 | 0.115938 |
- | ^ from 1995 onwards | + | |
==== Urea production ==== | ==== Urea production ==== | ||
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==== Chlor-alkali industry ==== | ==== Chlor-alkali industry ==== | ||
- | For the mercury (Hg) losses from the Chlor-alkali industry, Germany used the yearly published data from OSPAR on the plant specific production capacity for the AD and the plant specific emissions from the chlor-alkali industry. Because of the BAT (best available technique) conclusion for the Chlor-alkali industry, the production based upon the amalgam process has stopped in 2017. Most production sites switched to membrane technology. | + | For the mercury (Hg) losses from the Chlor-alkali industry, Germany used the yearly published data from OSPAR [(ODIMS (OSPAR Data & Information Management System); https:// |
However, emissions of Hg are still ocurring, because two production sites still continue to uses the amalgam process for the production of certain alcoholates; | However, emissions of Hg are still ocurring, because two production sites still continue to uses the amalgam process for the production of certain alcoholates; | ||
As from 2018 PRTR data is used to determine mercury emissions belonging to the alcoholate production. Due to a delay of the 2019 PRTR data the 2018 emission value is used also in 2019 and 2020. | As from 2018 PRTR data is used to determine mercury emissions belonging to the alcoholate production. Due to a delay of the 2019 PRTR data the 2018 emission value is used also in 2019 and 2020. | ||
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For SO< | For SO< | ||
- | From Submission 2022 the SO< | + | From Submission 2022 onwards, |
- | **Table 6**: SO< | + | Otherwise no recalculations of SO< |
- | ^ Year ^ SO<sub>2</ | + | |
- | | 1990 | 23.47 | | + | |
- | | 1991 | 22.47 | | + | |
- | | 1992 | 22.07 | | + | |
- | | 1993 | 20.14 | | + | |
- | | 1994 | 18.86 | | + | |
- | | 1995 | 23.03 | | + | |
- | | 1996 | 20.98 | | + | |
- | | 1997 | 22.23 | | + | |
- | | 1998 | 23.58 | | + | |
- | | 1999 | 24.03 | | + | |
- | | 2000 | 24.04 | | + | |
- | | 2001 | 23.01 | | + | |
- | | 2002 | 22.89 | | + | |
- | | 2003 | 23.78 | | + | |
- | | 2004 | 25.65 | | + | |
- | | 2005 | 26.54 | | + | |
- | | 2006 | 26.83 | | + | |
- | | 2007 | 25.74 | | + | |
- | | 2008 | 24.1 | | + | |
- | | 2009 | 19.87 | | + | |
- | | 2010 | 20.39 | | + | |
- | | 2011 | 19.79 | | + | |
- | | 2012 | 18.25 | | + | |
- | | 2013 | 16.94 | | + | |
- | | 2014 | 13.89 | | + | |
- | | 2015 | 12.59 | | + | |
- | | 2016 | 11.06 | | + | |
- | | 2017 | 10.14 | | + | |
- | | 2018 | 10.22 | | + | |
- | | 2019 | 9.96 | | + | |
- | | 2020 | 9.69 | | + | |
- | So far Germany reported NH< | + | <WRAP center round info 65%> |
- | Therefore, instead of nitric fertilizer production Germany reports NH< | + | For **pollutant-specific information on recalculated emission estimates for Base Year and 2021**, please see the pollutant specific recalculation tables following [[general: |
- | + | ||
- | **Table 7**: NH< | + | |
- | ^ ^ Subm2022 | + | |
- | ^ Product | + | |
- | ^ ^ AD ^ EM ^ AD ^ EM ^ EM ^ EM ^ EM ^ | + | |
- | ^ Pollutant | + | |
- | ^ Unit ^ t ^ t ^ t ^ t ^ t ^ t ^ t ^ | + | |
- | ^ 1990 | 2, | + | |
- | ^ 1991 | 2, | + | |
- | ^ 1992 | 2, | + | |
- | ^ 1993 | 2, | + | |
- | ^ 1994 | 2, | + | |
- | ^ 1995 | 2, | + | |
- | ^ 1996 | 2, | + | |
- | ^ 1997 | 2, | + | |
- | ^ 1998 | 2, | + | |
- | ^ 1999 | 2, | + | |
- | ^ 2000 | 2, | + | |
- | ^ 2001 | 2, | + | |
- | ^ 2002 | 2, | + | |
- | ^ 2003 | 2, | + | |
- | ^ 2004 | 2, | + | |
- | ^ 2005 | 2, | + | |
- | ^ 2006 | 2, | + | |
- | ^ 2007 | 2, | + | |
- | ^ 2008 | 2, | + | |
- | ^ 2009 | 3, | + | |
- | ^ 2010 | 3, | + | |
- | ^ 2011 | 1, | + | |
- | ^ 2012 | 1, | + | |
- | ^ 2013 | 1, | + | |
- | ^ 2014 | 1, | + | |
- | ^ 2015 | 1, | + | |
- | ^ 2016 | 1, | + | |
- | ^ 2017 | 2, | + | |
- | ^ 2018 | 2, | + | |
- | ^ 2019 | 2, | + | |
- | ^ 2020 | 2, | + | |
- | + | ||
- | <WRAP center round info 60%> | + | |
- | For **pollutant-specific information on recalculated emission estimates for Base Year and 2019**, please see the pollutant specific recalculation tables following [[general: | + | |
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