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sector:ippu:chemical_industry:other:start [2022/03/29 11:33] – [Chlor-alkali industry] reichel | sector:ippu:chemical_industry:other:start [2025/02/07 12:09] (current) – [Short description] zheng | ||
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__Table 1: Overview of emission sources covered__ | __Table 1: Overview of emission sources covered__ | ||
- | ^ Emission sources | + | ^ Emission sources |
- | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] | + | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] |
- | | [[#Carbon Black|Carbon Black]] | + | | [[#Carbon Black|Carbon Black]] |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
{{page> | {{page> | ||
===== Method ===== | ===== Method ===== | ||
- | ==== Large Volume Organic | + | ==== Large volume organic |
- | The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | + | The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))]. |
__These chemicals__ comprise: | __These chemicals__ comprise: | ||
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The emission factors for the production of organic chemicals as shown in Tables 2 and 3 are derived from best reference documents for polymers and LVOC mostly for the early years. For later years, plant-specific data on an aggregated level were used. | The emission factors for the production of organic chemicals as shown in Tables 2 and 3 are derived from best reference documents for polymers and LVOC mostly for the early years. For later years, plant-specific data on an aggregated level were used. | ||
- | __Table 2: national | + | __Table 2: National |
- | ^ Product | + | ^ ^ Acrylonitrile |
- | ^ from 1990-1994 | + | ^ 1990-1994 |
- | ^ 1995 | 0.07 | 0.02 | 0.4 | C | 0.06 | 0.02 | 0.04 | 0.2 | 0.2 | 0.02 | 0.2 | | + | ^ 1995 |
- | ^ 1996 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1996 |
- | ^ 1997 | 0.05 | 0.015 | 0.3 | C | 0.045 | 0.015 | 0.04 | 0.15 | 0.15 | 0.02 | 0.15 | | + | ^ 1997 |
- | ^ 1998 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1998 |
- | ^ 1999 | 0.04 | 0.012 | 0.25 | C | 0.04 | 0.012 | 0.04 | 0.12 | 0.12 | 0.02 | 0.12 | | + | ^ 1999 |
- | ^ from 2000 | + | ^ from 2000 | 0.035 | 0.01 | 0.2 |
- | __Table 3: national NMVOC emission factors for producing polymers, in kg/t__ | ||
- | ^ products | + | __Table 3: National NMVOC emission factors for the production of polymers, in kg/t__ |
- | ^ | + | |
- | ^ from 1990 to 1994 | + | ^ ^ Polyethylene (PE) |
- | ^ 1995 | 2.2 | 1 | 1 | 0.6 | 0.25 | 0.6 | | + | ^ | Low density (LD) |
- | ^ 1996 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1990-1994 | 8 | 6 | 8 | 1 |
- | ^ 1997 | 1.6 | 0.75 | 0.75 | 0.4 | 0.25 | 0.5 | | + | ^ 1995 |
- | ^ 1998 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1996 |
- | ^ 1999 | 1.3 | 0.6 | 0.6 | 0.32 | 0.25 | 0.4 | | + | ^ 1997 |
- | ^ from 2000 | + | ^ 1998 |
+ | ^ 1999 | ||
+ | ^ from 2000 | 1.1 | 0.5 | 0.5 | 0.27 | 0.14 | 0.3 | | ||
==== Carbon Black ==== | ==== Carbon Black ==== | ||
- | The figures for carbon black production in the new German Länder in 1990 were taken from the Statistical Yearbook (Statistisches Jahrbuch) for the Federal Republic of Germany; the figures | + | The figures for carbon black production in the new German Länder in 1990 were taken from the Statistical Yearbook (Statistisches Jahrbuch) for the Federal Republic of Germany; the production |
From 2005 onwards, Germany uses activity data calculated from the CO< | From 2005 onwards, Germany uses activity data calculated from the CO< | ||
__Table 4: Emission factors of carbon black in Germany, in kg/t__ | __Table 4: Emission factors of carbon black in Germany, in kg/t__ | ||
- | ^ Pollutant | + | ^ ^ CO ^ SO< |
- | ^ 1990 | 4.80 | 19.16 | 0.28 | | + | ^ 1990 |
- | ^ 1991 | 4.60 | 19.01 | 0.28 | | + | ^ 1991 |
- | ^ 1992 | 4.40 | 18.50 | + | ^ 1992 |
- | ^ 1993 | 4.20 | 18.00 | 0.26 | | + | ^ 1993 |
- | ^ 1994 | 4.00 | 17.50 | + | ^ 1994 |
- | ^ 1995 | 3.75 | 17.00 | 0.25 | 0.23 | 0.12 | + | ^ 1995 |
- | ^ 1996 | 3.50 | 16.00 | 0.25 | 0.23 | + | ^ 1996 |
- | ^ 1997 | 3.25 | 15.00 | 0.25 | 0.23 | + | ^ 1997 |
- | ^ 1998 | 3.00 | 14.00 | 0.25 | 0.23 | + | ^ 1998 |
- | ^ 1999 | 2.90 | 13.40 | 0.25 | 0.23 | + | ^ 1999 |
- | ^ 2000 | 2.80 | 12.80 | 0.25 | 0.23 | + | ^ 2000 |
- | ^ 2001 | 2.70 | 12.54 | 0.25 | 0.23 | + | ^ 2001 |
- | ^ 2002 | 2.65 | 12.28 | 0.25 | 0.23 | 0.12 | + | ^ 2002 |
- | ^ 2003 | 2.60 | 12.00 | 0.25 | 0.23 | 0.12 | + | ^ 2003 |
- | ^ 2004 | 2.55 | 11.70 | 0.25 | 0.23 | + | ^ 2004 |
- | ^ 2005 | 2.50 | 11.50 | 0.25 | 0.23 | + | ^ 2005 |
- | ^ 2006 | 2.50 | 11.20 | 0.24 | 0.22 | + | ^ 2006 |
- | ^ 2007 | 2.50 | 10.90 | 0.23 | 0.21 | + | ^ 2007 |
- | ^ 2008 | 2.50 | 10.60 | 0.22 | 0.20 | + | ^ 2008 |
- | ^ 2009 | 2.50 | 10.30 | 0.21 | 0.19 | + | ^ 2009 |
- | ^ from 2010 | 2.50 | 10.00 | 0.20 | 0.18 | 0.10 | + | ^ from 2010 | 2.50 | 10.00 |
==== Fertilizer production ==== | ==== Fertilizer production ==== | ||
- | The activity data is also extracted from national production statistics by the Federal Statistical Office< | + | The activity data is also extracted from national production statistics by the Federal Statistical Office[(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] and consists of mono and multicomponent fertilizers. |
The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | ||
- | __Table 5: Emission factors of fertilizers in Germany, in kg/t__ | + | __Table 5: Emission factors of fertilizers in Germany__ |
- | ^ Product | + | ^ ^ PM< |
- | ^ Pollutant | + | ^ 1990 |
- | ^ 1990 | + | ^ 1991-1994 | NA |
- | ^ from 1991 to 1994 | NA | NA | 2 | | + | ^ from 1995 | 0.115938 |
- | ^ from 1995 onwards | + | |
==== Urea production ==== | ==== Urea production ==== | ||
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==== Chlor-alkali industry ==== | ==== Chlor-alkali industry ==== | ||
- | For the mercury (Hg) losses from the Chlor-alkali industry, Germany used the yearly published data from OSPAR on the plant specific production capacity for the AD and the plant specific emissions from the chlor-alkali industry. Because of the BAT (best available technique) conclusion for the Chlor-alkali industry, the production based upon the amalgam process has stopped in 2017. Most production sites switched to membrane technology. | + | For the mercury (Hg) losses from the Chlor-alkali industry, Germany used the yearly published data from OSPAR [(ODIMS (OSPAR Data & Information Management System); https:// |
However, emissions of Hg are still ocurring, because two production sites still continue to uses the amalgam process for the production of certain alcoholates; | However, emissions of Hg are still ocurring, because two production sites still continue to uses the amalgam process for the production of certain alcoholates; | ||
- | As from 2018 PRTR data is used to determine mercury emissions belonging to the alcoholate production. Due to a delay of the 2019 PRTR data the 2018 emission value is used also in 2019 and 2020. | + | As from 2018 PRTR data is used to determine mercury emissions belonging to the alcoholate production. |
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For SO< | For SO< | ||
- | From Submission 2022 the SO< | + | From Submission 2022 onwards, |
- | + | ||
- | **Table 6**: SO< | + | |
- | ^ Year ^ SO< | + | |
- | | 1990 | 23.47 | | + | |
- | | 1991 | 22.47 | | + | |
- | | 1992 | 22.07 | | + | |
- | | 1993 | 20.14 | | + | |
- | | 1994 | 18.86 | | + | |
- | | 1995 | 23.03 | | + | |
- | | 1996 | 20.98 | | + | |
- | | 1997 | 22.23 | | + | |
- | | 1998 | 23.58 | | + | |
- | | 1999 | 24.03 | | + | |
- | | 2000 | 24.04 | | + | |
- | | 2001 | 23.01 | | + | |
- | | 2002 | 22.89 | | + | |
- | | 2003 | 23.78 | | + | |
- | | 2004 | 25.65 | | + | |
- | | 2005 | 26.54 | | + | |
- | | 2006 | 26.83 | | + | |
- | | 2007 | 25.74 | | + | |
- | | 2008 | 24.1 | | + | |
- | | 2009 | 19.87 | | + | |
- | | 2010 | 20.39 | | + | |
- | | 2011 | 19.79 | | + | |
- | | 2012 | 18.25 | | + | |
- | | 2013 | 16.94 | | + | |
- | | 2014 | 13.89 | | + | |
- | | 2015 | 12.59 | | + | |
- | | 2016 | 11.06 | | + | |
- | | 2017 | 10.14 | | + | |
- | | 2018 | 10.22 | | + | |
- | | 2019 | 9.96 | | + | |
- | | 2020 | 9.69 | | + | |
- | + | ||
- | So far Germany | + | |
- | Therefore, instead of nitric fertilizer production Germany reports NH< | + | |
- | **Table 7**: NH<sub>3</ | + | Otherwise no recalculations of SO<sub>2</ |
- | ^ ^ Subm2022 | + | |
- | ^ Product | + | |
- | ^ ^ AD ^ EM ^ AD ^ EM ^ EM ^ EM ^ EM ^ | + | |
- | ^ Pollutant | + | |
- | ^ Unit ^ t ^ t ^ t ^ t ^ t ^ t ^ t ^ | + | |
- | ^ 1990 | 2, | + | |
- | ^ 1991 | 2, | + | |
- | ^ 1992 | 2, | + | |
- | ^ 1993 | 2, | + | |
- | ^ 1994 | 2, | + | |
- | ^ 1995 | 2, | + | |
- | ^ 1996 | 2, | + | |
- | ^ 1997 | 2, | + | |
- | ^ 1998 | 2, | + | |
- | ^ 1999 | 2, | + | |
- | ^ 2000 | 2, | + | |
- | ^ 2001 | 2, | + | |
- | ^ 2002 | 2, | + | |
- | ^ 2003 | 2, | + | |
- | ^ 2004 | 2, | + | |
- | ^ 2005 | 2, | + | |
- | ^ 2006 | 2, | + | |
- | ^ 2007 | 2, | + | |
- | ^ 2008 | 2, | + | |
- | ^ 2009 | 3, | + | |
- | ^ 2010 | 3, | + | |
- | ^ 2011 | 1, | + | |
- | ^ 2012 | 1, | + | |
- | ^ 2013 | 1, | + | |
- | ^ 2014 | 1, | + | |
- | ^ 2015 | 1, | + | |
- | ^ 2016 | 1, | + | |
- | ^ 2017 | 2, | + | |
- | ^ 2018 | 2, | + | |
- | ^ 2019 | 2, | + | |
- | ^ 2020 | 2, | + | |
- | <WRAP center round info 60%> | + | <WRAP center round info 65%> |
- | For **pollutant-specific information on recalculated emission estimates for Base Year and 2019**, please see the pollutant specific recalculation tables following [[general: | + | For **pollutant-specific information on recalculated emission estimates for Base Year and 2021**, please see the pollutant specific recalculation tables following [[general: |
</ | </ | ||
===== Planned improvements ===== | ===== Planned improvements ===== | ||
- | For the mercury losses from the Chlor-alkali industry, because of the BAT conclusion for the Chlor-alkali industry the production has stopped in 2017. However, emissions of Hg are still ocurring, because two plants are still producing alcoholates and dithionite and were so far reported by CEFIC to OSPAR based on BAT regulation for Chlor-alkali production. Since the OSPAR convention does not request to report the Hg-emissions from dithionite and alcoholate production, CEFIC no longer reports these emissions to OSPAR. | + | There are no planned improvements. |
- | Germany is trying to ensure reporting of Hg emissions for that sources. | + | |