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sector:ippu:chemical_industry:other:start [2022/03/08 10:15] – [Recalculations] kuntze | sector:ippu:chemical_industry:other:start [2022/03/29 09:33] – [Chlor-alkali industry] reichel | ||
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__Table 1: Overview of emission sources covered__ | __Table 1: Overview of emission sources covered__ | ||
- | ^ Emission sources | + | ^ Emission sources |
- | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] | + | | [[#Large Volume Organic chemicals|Large Volume Organic chemicals]] |
- | | [[#Carbon Black|Carbon Black]] | + | | [[#Carbon Black|Carbon Black]] |
- | | [[#Fertilizers|Fertilizers]] | + | | [[#fertilizer_production|Fertilizers]] |
- | | [[# | + | | [[# |
- | | [[# | + | | [[# |
{{page> | {{page> | ||
===== Method ===== | ===== Method ===== | ||
- | === Large Volume Organic chemicals === | + | ==== Large Volume Organic chemicals |
The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | The annual production volumes for all large volume organic chemicals are extracted from national production statistics by the Federal Statistical Office [(DESTATIS, Fachserie 4, Reihe 3.1, Produzierendes Gewerbe, Produktion im Produzierenden Gewerbe (“manufacturing industry; production in the manufacturing industry”))] | ||
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^ from 2000 | 1.1 | 0.5 | 0.5 | 0.27 | 0.14 | 0.3 | | ^ from 2000 | 1.1 | 0.5 | 0.5 | 0.27 | 0.14 | 0.3 | | ||
- | === Carbon Black === | + | ==== Carbon Black ==== |
The figures for carbon black production in the new German Länder in 1990 were taken from the Statistical Yearbook (Statistisches Jahrbuch) for the Federal Republic of Germany; the figures for 1991 and 1992 were estimated, due to confidentiality requirements. The other data for carbon-black production as of 1990 were obtained from national production statistics< | The figures for carbon black production in the new German Länder in 1990 were taken from the Statistical Yearbook (Statistisches Jahrbuch) for the Federal Republic of Germany; the figures for 1991 and 1992 were estimated, due to confidentiality requirements. The other data for carbon-black production as of 1990 were obtained from national production statistics< | ||
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- | === Fertilizer production === | + | ==== Fertilizer production |
- | The activity data is also extracted from national production statistics by the Federal Statistical Office< | + | The activity data is also extracted from national production statistics by the Federal Statistical Office< |
The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | The emission factors are country specific (Jörß et al. 2006)[(Umweltbundesamt, | ||
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^ from 1995 onwards | ^ from 1995 onwards | ||
- | === Urea production === | + | ==== Urea production |
The activity data is from the federal statistical office of Germany (GP 2015 31 300). The amount of urea is reported there in t-N. | The activity data is from the federal statistical office of Germany (GP 2015 31 300). The amount of urea is reported there in t-N. | ||
- | As the emission factor is in kg/t urea the reported amount of urea in t-N is multiplied with the molar mass of urea and divided with the molar mass of nitric (60,06/ | + | As the emission factor is in kg/t urea, the reported amount of urea in t-N is multiplied with the molar mass of urea and divided with the molar mass of nitric (60.06/ |
- | ARurea | + | AR of urea (in t) = AR of urea (in t-N) * (molar mass of urea)/ (molar mass of N) |
- | The emission factor is a T2 EF from the EMEP/EEA Guidebook 2019, chapter 3.2.2, | + | The emission factor |
- | The value is 2.5 kg /t urea | + | |
- | === Sulphuric acid === | + | ==== Sulphuric acid ==== |
The activity data for sulphuric acid production is from the Federal Statistical Office of Germany. | The activity data for sulphuric acid production is from the Federal Statistical Office of Germany. | ||
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For the SO< | For the SO< | ||
- | === Chlor-alkali industry === | + | ==== Chlor-alkali industry ==== |
+ | |||
+ | For the mercury (Hg) losses from the Chlor-alkali industry, Germany used the yearly published data from OSPAR on the plant specific production capacity for the AD and the plant specific emissions from the chlor-alkali industry. Because of the BAT (best available technique) conclusion for the Chlor-alkali industry, the production based upon the amalgam process has stopped in 2017. Most production sites switched to membrane technology. | ||
+ | However, emissions of Hg are still ocurring, because two production sites still continue to uses the amalgam process for the production of certain alcoholates; | ||
+ | As from 2018 PRTR data is used to determine mercury emissions belonging to the alcoholate production. Due to a delay of the 2019 PRTR data the 2018 emission value is used also in 2019 and 2020. | ||
- | For the mercury losses from the Chlor-alkali industry, Germany uses the yearly published data from OSPAR on the plant specific production capacity for the AD and the plant specific emissions from the chlor-alkali industry. Because of the BAT (best available technique) conclusion for the Chlor-alkali industry, the production has stopped in 2017. However, emissions of Hg are still ocurring, because two plants still produce alcoholates and dithionite and are not regulated by the BAT conclusions for Chlor-alkali production. In both plants Chlor-alkali was also produced. The Hg-emissions from the production of dithionite and alcoholates | ||
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**Table 6**: SO< | **Table 6**: SO< | ||
- | ^ Year ^ SO2 in kt ^ | + | ^ Year ^ |
- | | 1990 | 23.47 | | + | | 1990 | |
- | | 1991 | 22.47 | | + | | 1991 | |
- | | 1992 | 22.07 | | + | | 1992 | |
- | | 1993 | 20.14 | | + | | 1993 | |
- | | 1994 | 18.86 | | + | | 1994 | |
- | | 1995 | 23.03 | | + | | 1995 | |
- | | 1996 | 20.98 | | + | | 1996 | |
- | | 1997 | 22.23 | | + | | 1997 | |
- | | 1998 | 23.58 | | + | | 1998 | |
- | | 1999 | 24.03 | | + | | 1999 | |
- | | 2000 | 24.04 | | + | | 2000 | |
- | | 2001 | 23.01 | | + | | 2001 | |
- | | 2002 | 22.89 | | + | | 2002 | |
- | | 2003 | 23.78 | | + | | 2003 | |
- | | 2004 | 25.65 | | + | | 2004 | |
- | | 2005 | 26.54 | | + | | 2005 | |
- | | 2006 | 26.83 | | + | | 2006 | |
- | | 2007 | 25.74 | | + | | 2007 | |
- | | 2008 | 24.1 | + | | 2008 | 24.1 | |
- | | 2009 | 19.87 | | + | | 2009 | |
- | | 2010 | 20.39 | | + | | 2010 | |
- | | 2011 | 19.79 | | + | | 2011 | |
- | | 2012 | 18.25 | | + | | 2012 | |
- | | 2013 | 16.94 | | + | | 2013 | |
- | | 2014 | 13.89 | | + | | 2014 | |
- | | 2015 | 12.59 | | + | | 2015 | |
- | | 2016 | 11.06 | | + | | 2016 | |
- | | 2017 | 10.14 | | + | | 2017 | |
- | | 2018 | 10.22 | | + | | 2018 | |
- | | 2019 | 9.96 | + | | 2019 | 9.96 | |
- | | 2020 | 9.69 | + | | 2020 | 9.69 | |
- | + | ||
- | So far Germany reported NH3 and TSP emissions from nitric fertilizer production. Germany has decided to not report this category anymore. And to report instead emissions from the category urea production. There are several reasons to do this. The category nitric fertilizer production is a country specific category. There is no method described in the EMEP/EEA Guidebook for nitric fertilizer production. Since several years Germany has no data source for the activity data for nitric fertilizer production. During the investigation Germany came to the assumption that there is a double counting of TSP emissions from nitric fertilizer production and fertilizer production. | + | |
- | instead of the nitric fertilizer production Germany reports since the submission 2022 NH3 emissions from urea production based on the Emep/EEA Guidebook method, using statistical data from the federal statistical office, which will be available in future too. Whith this step Germany as improved the quality of the reporting of the fertilizer porduction from Germany. | + | |
- | **Table 7**: NH3 and TSP emissions from urea production | + | So far Germany reported NH< |
- | ^ Year ^ SO2 in kt ^ | + | Therefore, instead of nitric fertilizer production Germany reports NH< |
- | | 1990 | 23.47 | | + | |
- | | 1991 | 22.47 | | + | |
- | | 1992 | 22.07 | | + | |
- | | 1993 | 20.14 | | + | |
- | | 1994 | 18.86 | | + | |
- | | 1995 | 23.03 | | + | |
- | | 1996 | 20.98 | | + | |
- | | 1997 | 22.23 | | + | |
- | | 1998 | 23.58 | | + | |
- | | 1999 | 24.03 | | + | |
- | | 2000 | 24.04 | | + | |
- | | 2001 | 23.01 | | + | |
- | | 2002 | 22.89 | | + | |
- | | 2003 | 23.78 | | + | |
- | | 2004 | 25.65 | | + | |
- | | 2005 | 26.54 | | + | |
- | | 2006 | 26.83 | | + | |
- | | 2007 | 25.74 | | + | |
- | | 2008 | 24.1 | | + | |
- | | 2009 | 19.87 | | + | |
- | | 2010 | 20.39 | | + | |
- | | 2011 | 19.79 | | + | |
- | | 2012 | 18.25 | | + | |
- | | 2013 | 16.94 | | + | |
- | | 2014 | 13.89 | | + | |
- | | 2015 | 12.59 | | + | |
- | | 2016 | 11.06 | | + | |
- | | 2017 | 10.14 | | + | |
- | | 2018 | 10.22 | | + | |
- | | 2019 | 9.96 | | + | |
- | | 2020 | 9.69 | | + | |
- | + | ||
+ | **Table 7**: NH< | ||
+ | ^ ^ Subm2022 | ||
+ | ^ Product | ||
+ | ^ ^ AD ^ EM ^ AD ^ EM ^ EM ^ EM ^ EM ^ | ||
+ | ^ Pollutant | ||
+ | ^ Unit ^ t ^ t ^ t ^ t ^ t ^ t ^ t ^ | ||
+ | ^ 1990 | 2, | ||
+ | ^ 1991 | 2, | ||
+ | ^ 1992 | 2, | ||
+ | ^ 1993 | 2, | ||
+ | ^ 1994 | 2, | ||
+ | ^ 1995 | 2, | ||
+ | ^ 1996 | 2, | ||
+ | ^ 1997 | 2, | ||
+ | ^ 1998 | 2, | ||
+ | ^ 1999 | 2, | ||
+ | ^ 2000 | 2, | ||
+ | ^ 2001 | 2, | ||
+ | ^ 2002 | 2, | ||
+ | ^ 2003 | 2, | ||
+ | ^ 2004 | 2, | ||
+ | ^ 2005 | 2, | ||
+ | ^ 2006 | 2, | ||
+ | ^ 2007 | 2, | ||
+ | ^ 2008 | 2, | ||
+ | ^ 2009 | 3, | ||
+ | ^ 2010 | 3, | ||
+ | ^ 2011 | 1, | ||
+ | ^ 2012 | 1, | ||
+ | ^ 2013 | 1, | ||
+ | ^ 2014 | 1, | ||
+ | ^ 2015 | 1, | ||
+ | ^ 2016 | 1, | ||
+ | ^ 2017 | 2, | ||
+ | ^ 2018 | 2, | ||
+ | ^ 2019 | 2, | ||
+ | ^ 2020 | 2, | ||
- | <WRAP center round info 100%> | + | <WRAP center round info 60%> |
- | For specific | + | For **pollutant-specific |
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